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         Thiophosphoryl Chloride 98%; Phosphorous Sul fochloride 98%;

         Phosphorous Thiochloride 98%;Phosphorothioic trichloride 98%

                  Thiophoryl trichloride 98%

  CAS NO:3982-91-0  UN Number:1837 .Class or Division:8.1,Ⅱ Packaging Group.

  Main Hazard: Corrosive liquid.H.S.NO:28121049 or 90

  Shipping Name: Thiophosphoryl Chloride

  Make out the invoices of 17% value added tax

  Molecular formula:PSCL3 Molecular weihgt:169.4

  Structural Formula:

  Physical and chemical properties:

   Colorless transparent liquid, density 1.635kg/L ,boiling point 125℃,refractive index 1.635(25℃).It can not dissolve in water ,but can dissolve in some organic solvents, such as methylbenzene, carbon tetrachloride ,carbon disulfide ,trichloromethane and others. It deconposes slowly in water, and decomposes rapidly in alkali solution.

                            Quality and Technical Index:

PSCL3 Content:

98%

Appearance:

Colourless transparent liquid

Water-wash the decrement law:

≤0.5%

The agriculture chemical of organic phosphorus and intermedia of some medicine

Or

Appearance

Colorless transparent liquid

Boiling point

125℃

Refractive index

1.635(20℃)

Loss on washing

≤1%

PSCL3  Purity

≥98%

     Toxicity: Its toxicity is very high. It has stimulation on human's skin and membrana mucosa. The stimulation on eyes is very severe.
Pneumonectasias may be caused ,if it is sucked.

  Uses:

  Used as organic phosphorus pesticide and some medicine intermediate products. It is mainly used to produce the organic pesticides' materials of Methamidophos, Acephate,Parathion etc.

  Thiophosphoryl chloride indexes:
  Appearance :colorless transparent liquid;

  Content:≥98%;Loss quantity of water washihg :≤1%

  Output:980tons/every month,15,000 tons/every year

  Packing: 200L steel drum or UN iron drum

  Net weight:200kg or 250kg or 300kg/steel drum or iron drum

  iron drum, plastic drum, steel drum

  16tons、20tons、30tons、32tons

                       Please click :Thiophosphoryl chloride label

            Material Safety Data Sheet and technical description pictures

Thiophosphoryl chloride : Gas Chromatography analysis method

ASTM Reference Number:
Prior Method Number:
Impurity Assay of PSCl3 (Thiophosphoryl Chloride) by Gas Chromatography
Scope
Product:
Properties: Assay
Applicable Range:
Exclusions:
Analytical Technique
Gas Chromatography
Method Summary
Portions of the PSCl3 are injected in neat form into the gas
chromatograph and an area percent report is produced. A thermal
conductivity detector and a split/splitless capillary inlet are used.
Safety - MSDS Citations
All compounds used in this analytical procedure require caution when handling.Follow the handling precautions in the MSDS for each one.
a) Thiophosphoryl chloride (PSCl3).
Required Equipment
a) Gas Chromatograph. Hewlett Packard 5890 or equivalent, equipped with
a thermal conductivity detector (TCD), a split/splitless inlet with a
cup splitter glass liner packed with glass wool, and a model 7673 or
equivalent automatic sampler.
b) Data Acquisition and Analysis Device. VAX MULTICHROM or equivalent
chromatography data collection and processing system.A stand alone
integrator may also be used.
c) Gas Chromatographic Column. 0.53mm diameter X 30 meter length, 5.0μm
film thickness DB-1 or equivalent capillary column (J&W catalog number 125-1035).
d) Syringe. 10μl automatic sampler syringe (Hewlett Packard catalog
number 5181-1267 or equivalent).
e) Crimp Top Vials. Hewlett Packard 2-ml glass crimp top vials with
Teflon lined silicon septa (Hewlett Packard catalog number 5061-3350 or equivalent).
f) Disposable Pasteur Pipets.Glass,disposable pipets,(Fisher Scientific catalog number 13-678-20A or equivalent).
Instrument Conditions
Required Chemicals
a) Thiophosphoryl chloride,98%, Aldrich Chemical Company, catalog
number 22,429-4.
b) Acetone, reagent grade.
Required Standard Reference Materials
Calibration/Standardization/SQC
Inject 2μl of the reference PSCl3 and create a calibration file with the peak names and retention time windows as in the attached chromatogram.
Detailed Procedure
The samples are analyzed in neat form according the GC method below:
GC Conditions:
a) Carrier Gas: Helium @ 5.0ml/minute at 35°C
b) Detector: Thermal Conductivity Detector, low sensitivity, range 0
c) Detector Temperature: 260°C
d) Detector Make-Up Flow:1.5 ml/minute
e) Reference Gas Flow:20ml/minute(total of column,make-up and reference)
f) Injection Mode: Split, with split flow approximately 30ml/minute.
?? Use an automatic sampler if possible.
g) Inlet Temperature:250°C
h) Oven Temperature Program:
Initial Temperature: 35°C
Initial Time 10 minutes
Program Rate: 15°C/minute
Final Temperature: 250°C
Final Time:10 minutes (NOTE:The run may be stopped at 24 minutes if it is certain that no other components are in the sample.)
Injection Size:2μl(NOTE:After the sampler has injected the sample, remove the syringe and clean it thoroughly with water and then with acetone.
Failure to do this will result in the plunger freezing in the barrel of the syringe.)
Calculations
Area percent data is sufficient for this analysis. Information Precision Statements:
Revision History:
Reference Info:

  Copyright:Lianyungang Dongjin Chemical Co., Ltd Tel:0086-0518-87319228  
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